Fracture in elongational flow of two low-density polyethylene melts
نویسندگان
چکیده
Abstract Samples of two commercial low-density polyethylene melts were investigated with respect to their fracture behavior in controlled uniaxial extensional flow at constant strain rate a filament stretching rheometer. In order assess the possible influence grain boundaries on fracture, samples prepared by three different types pre-treatment: compression molding (1) virgin pellets used as received, (2) homogenized twin-screw extruder, and (3) that milled into powder cryogenic grinding under liquid nitrogen. The elongational stress growth data analyzed Extended Hierarchical Multi-mode Molecular Stress Function (EHMMSF) model developed Wagner et al. (Rheol. Acta 61, 281-298 (2022)) for long-chain branched (LCB) polymer melts. EHMMSF quantifies including maximum viscosity LDPE based solely linear-viscoelastic relaxation spectrum nonlinear material parameters, dilution modulus G D characteristic stretch parameter $${\overline{\lambda}}_m$$ λ ¯ m . Within experimental accuracy, predictions are excellent agreement melts, independent preparation method used. At sufficiently high rates, filaments was observed is general accordance entropic criterion implemented model. High-speed videography reveals preceded parabolic crack opening, which elastic has been earlier monodisperse polystyrene solutions. Here, first time, we demonstrate appearance opening process polydisperse
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ژورنال
عنوان ژورنال: Rheologica Acta
سال: 2023
ISSN: ['0035-4511', '1435-1528']
DOI: https://doi.org/10.1007/s00397-023-01392-1